تبدیل نوری آلاینده زیست محیطی هیدروژن سولفید و تولید سوخت هیدروژن با استفاده از کاتالیزگر نانوکامپوزیتی مغناطیسی پایه کربن
محورهای موضوعی : مهندسی شیمی (آلودگیهای محیط زیست)مجید غنیمتی 1 * , محسن لشگری 2 , مهچهره ثابتی 3
1 - دانشگاه تحصیلات تکمیلی علوم پایه زنجان
2 - دانشگاه تحصیلات تکمیلی علوم پایه زنجان
3 - دانشگاه تحصیلات تکمیلی علوم پایه زنجان
کلید واژه: فوتوتخریب/تبدیل H2S, تولید هیدروژن, انرژی¬مواد نانوکامپوزیت مغناطیسی, نانولوله کربنی, ماده خطرناک, تبدیل آلاینده به سوخت, کاتالیزگر نیم¬رسانا,
چکیده مقاله :
هیدروژن سولفید یک آلاینده خطرناک زیست محیطی، خورنده و اشتعال پذیر است که در صنایع نفت و گاز ترش در مقیاس وسیع تولید می شود. یکی از استراتژی های پایدار برای حذف این آلاینده زیست محیطی و تبدیل آن به سوخت پاک هیدروژن، استفاده از منابع تجدید پذیر انرژی (فوتون) و سنتز نانوانرژی مواد نیم رسانا است. برای این منظور در پروژه حاضر ترکیب نانوساختار نیم رسانای مغناطیسی MgFe2O4 سنتز شد و برای تولید هیدروژن از طریق شکافت فوتوکاتالیستی محلول قلیایی H2S مورد استفاده قرار گرفت. شواهد تجربی نشان داد ترکیب سنتزی از توانایی لازم برای احیای پروتون و تولید هیدروژن برخوردار است. همچنین با سنتز ترکیب نانوکامپوزیتی مغناطیسی CNT/MgFe2O4 اثر تقویتی نانولوله کربنی بر فعالیت فوتوکاتالیست مذکور مطالعه شد. بررسی ها نشان داد حضور نانولوله کربنی از طریق افزایش مساحت سطح فوتوکاتالیست، کاهش فرایند بازترکیب الکترون-حفره و افزایش جذب فوتون، تولید هیدروژن را به مقدار قابل توجهی افزایش می دهد. سرعت آزادسازی هیدروژن 1284 میکرو مول بر ساعت به ازای 2/0 گرم فوتوکاتالیست بدست آمد که بیانگر آن است ماده ی نانوکامپوزیتی سنتز شده از توانایی بالایی برای حذف آلاینده و تولید سوخت هیدروژن برخوردار است.
Hydrogen sulfide is a dangerous, corrosive and flammable environmental pollutant that is generated at large scale in sour oil and gas industries. One of the sustainable strategies to remove this environmental pollutant and convert it into hydrogen clean fuel is the use of a renewable energy source (photon) and synthesis of semiconducting nanoenergy materials. To this end, in the present project, a nanostructured magnetic semiconducting MgFe2O4 compound was synthesized and applied for the production of hydrogen fuel through photocatalytic splitting of an alkaline H2S solution. The empirical evidence revealed that the synthesized material has an appropriate potency to reduce proton and produce hydrogen. Furthermore, by the synthesis of CNT/MgFe2O4 magnetic nanocomposite, the boosting effect of carbon nanotube (CNT) on the activity of the aforementioned photocatalyst was examined. A significant promotion in hydrogen production was observed in the presence of CNT and justified in terms of increasing the photocatalyst surface area, retarding the electron-hole recombination process and enhancing the photon absorption. The rate of hydrogen evolution was 1284 µmole/h per 0.2 g photocatalyst, indicating that the synthesized nanocomposite material has a high ability to remove the pollutant and produce hydrogen fuel.
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