Coagulant recovery from waterworks sludge by acid digestion method
Subject Areas : Water and wastewater technologyS Elaheh Mahdavian Ahagh 1 * , Fariba Ostovar 2
1 - University of Tehran
2 - Faculty member of Environmental Research Institute of ACECR
Keywords: Coagulant Acid digestionWater treatment plant SludgeAluminum,
Abstract :
Coagulation is a process that increases the tendency of small particles in an aqueous suspension to attach to one another and to surfaces such as the media in a filter bed and is applied through mixing coagulants such as aluminum sulfate (alum), ferric chloride and polyaluminum chloride with raw water. Sludge containing coagulant is formed after coagulation and through sedimentation of natural turbidity. Presence of high amounts of coagulant in waterworks sludge, increases environmental risks and disposal costs. Coagulants in sludge have high economic value. Therefore, if these coagulants recover, not only sludge disposal risks but also expenses related to supply of fresh coagulant in water or wastewater treatment plant may decrease. In this paper, researches conducted by acid digestion method for coagulant recovery from waterworks sludge are investigated. Amounts of coagulant recovery, advantages and disadvantages and economic aspects of this method are studied. Results of the investigation showed that using sulfuric acid is the best option for conducting acid digestion process because it is cheap and available. Moreover, if the purpose of recovering process is to achieve a recovered coagulant with a similar quality to the commercial ones, acid digestion method will not satisfy related standards.
1. Letterman RD, Yiacoumi S. Coagulation and Flocculation. In: Edzwald JK, editor. Water Quality & Treatment. sixth. Denver: American Water Works Association (awwa); 2011. p. 443–523.
2. Fouad MM, El-Gendy AS, Razek TMA. Evaluation of sludge handling using acidification and sequential aluminum coagulant recovery: Case study of El-sheikh zayed WTP. J Water Supply Res Technol - AQUA. 2017;66(6):403–15.
3. Crittenden JC, Trussell RR, Hand DW, Howe KJ, Tchobanoglous G. Residuals Management. In: MWH’s Water Treatment Principles and Design. Third. Hoboken, New Jersey: John Wiley & Sons, Inc.; 2012. p. 1906.
4. Ulmert H, Särner E. The ReAl Process – A combined membrane and precipitation process for recovery of Aluminum from waterwork sludge. Vatten [Internet]. 2005;61:273–81. Available from: http://www.tidskriftenvatten.se/wp-content/uploads/2017/04/48_article_2376.pdf
5. Babatunde AO, Zhao YQ. Constructive approaches towards water treatment works sludge management: An international review of beneficial re-uses. Crit Rev Environ Sci Technol. 2007;37(2):129–64.
6. 6. United States Environmental Protection Agency (USEPA). Drinking Water Treatment Plant Residuals Management Technical Report (EPA 820-R-11-003). Washington, DC; 2011.
7. 7. Huang C, Pan JR, Sun K, Liaw C. Reuse of water treatment plant sludge and dam sediment in brick-making. Water Sci Technol. 2001;44(10):273–7.
8. 8. Nair AT, Ahammed MM. Coagulant recovery from water treatment plant sludge and reuse in post-treatment of UASB reactor effluent treating municipal wastewater. Environ Sci Pollut Res. 2014;21(17):10407–18.
9. Titshall L, Hughes J. Characterisation of some South African water treatment residues and implications for land application. Water SA. 2005;31(3):299–307.
10. Keeley J, Smith AD, Judd SJ, Jarvis P. Reuse of recovered coagulants in water treatment : An investigation on the effect coagulant purity has on treatment performance. Sep Purif Technol. 2014;131:69–78.
11. Keeley J, Smith AD, Judd SJ, Jarvis P. Acidified and ultrafiltered recovered coagulants from water treatment works sludge for removal of phosphorus from wastewater. Water Res. 2016;88:380–8.
12. Anastas PT, Warner JC. Green chemistry: Theory and practice. Oxford: Oxford University Press.; 1998. 135 p.
13. Keeley J, Jarvis P, Judd SJ. Coagulant Recovery from Water Treatment Residuals : A Review of Applicable Technologies. Crit Rev Environ Sci Technol. 2014;44(24):2675–719.
14. Evuti AM, Lawal M. Recovery of coagulants from water works sludge : A review. Adv Appl Sci Res. 2011;2(6):410–7.
15. Lata S, Singh PK, Samadder SR. Regeneration of adsorbents and recovery of heavy metals: a review. Int J Environ Sci Technol. 2015;12(4):1461–78.
16. Crittenden JC, Trussell RR, Hand DW, Howe KJ, Tchobanoglous G. Coagulation and Flocculation. In: MWH’s Water Treatment Principles and Design. Third. Hoboken, New Jersey: John Wiley & Sons, Inc.; 2012. p. 1906.
17. Cornwell DA. WATER TREATMENT PLANT RESIDUALS MANAGEMENT. 5th editio. Letterman RD, editor. WATER QUALITY AND TREATMENT: A Handbook of Community Water Supplies. New York: McGraw Hill; 1999.
18. Cornwell DA, Vandermeyden C, Dillow G, Wang M. Landfilling of Water Treatment Plant Coagulant Sludges. Denver: AWWARF; 1992.
19. Jewell WM. Method of purifying water. US Patent 718,465, 1903.
20. Bishop MM, Rolan AT, Bailey TL, Cornwell DA. Testing of Alum Recovery for Solids Reduction and Reuse. J / Am Water Work Assoc. 1987;79(6):76–83.
21. Boaventura RAR, Duarte AAS, Almeida MF. Aluminum recovery from water treatment sludges. In: Proceedings of the IV International Conference on Water Supply and Water Quality [Internet]. 2000. p. 1–4. Available from: http://repositorium.sdum.uminho.pt/bitstream/1822/5906/1/ASDuarte_4%25C2%25BAWSWQ%2520Crac%25C3%25B3via_2000.pdf
22. Parsons SA, Daniels SJ. The use of recovered coagulants in wastewater treatment. Environ Technol. 1999;20(9):979–86.
23. Yang L, Han YX, Wang DT. High efficiency aluminum coagulant recovery from drinking water treatment plant sludge by using ultrasound assisted acidification. Adv Mater Res. 2013;777:60–4.
24. Cheng WP, Fu CH, Chen PH, Yu RF. Factors Affecting Aluminum Dissolve from Acidified Water Purification Sludge. Int J Chem Mol Eng [Internet]. 2014;8(8):878–81. Available from: https://pdfs.semanticscholar.org/8ef7/70ffa279a53e28de85e7dc6e2d3ce87a37b9.pdf
25. Ishikawa S, Ueda N, Okumura Y, Iida Y, Baba K. Recovery of coagulant from water supply plant sludge and its effect on clarification. J Mater Cycles Waste Manag. 2007;9:167–72.
26. Xu GR, Yan ZC, Wang YC, Wang N. Recycle of Alum recovered from water treatment sludge in chemically enhanced primary treatment. J Hazard Mater. 2009;161:663–9.
27. Xu GR, Yan ZC, Wang N, Li GB. Ferric coagulant recovered from coagulation sludge and its recycle in chemically enhanced primary treatment. Water Sci Technol. 2009;60(1):211–9.
28. Chen Y, Wang W, Wei M, Chen J, He J, Chiang Y, et al. Effects of Al-coagulant sludge characteristics on the efficiency of coagulants recovery by acidification. Environ Technol. 2012;33(22):2525–2530.
29. Yang L, Wei J, Zhang Y, Wang J, Wang D. Reuse of acid coagulant-recovered drinking waterworks sludge residual to remove phosphorus from wastewater. Appl Surf Sci [Internet]. 2014;305:337–46. Available from: http://dx.doi.org/10.1016/j.apsusc.2014.03.081
30. Vaezi F, Batebi F. Recovery of Iron Coagulants From Tehran Water-Treatment-Plant Sludge for Reusing in Textile Wastewater Treatment. Iran J Publ Heal. 2001;30:135–8.
31. Ayoub M, Abdelfattah A. A parametric study of alum recovery from water treatment sludge. Water Sci Technol [Internet]. 2016;74(2):516–23. Available from: http://wst.iwaponline.com/cgi/doi/10.2166/wst.2016.241.
32. Fouad MM, Razek TMA, Elgendy AS. Utilization of Drinking Water Treatment Slurry to Produce Aluminum Sulfate Coagulant. WATER Environ Res. 2017;(February):186–91.
33. Keeley J, Jarvis P, Judd SJ. An economic assessment of coagulant recovery from water treatment residuals. Desalination [Internet]. 2012;287:132–7. Available from: http://dx.doi.org/10.1016/j.desal.2011.09.013
34. Saunders MF, Roeder ML. Coagulant recovery: A critical assessment. Denver, CO: The Foundation; 1991.
35. Masschelein WJ, Devleminck R, Genot J. The feasibility of coagulant recycling by alkaline reaction of aluminium hydroxide sludges. Water Res. 1985;19(11):1363–8.