امکان سنجی نیترات زدایی از آب آشامیدنی با استفاده از بستر فتوکاتالیستی بتن فراتوانمند
محورهای موضوعی : تکنولوژی آب و فاضلابسما تجسسی 1 * , جلیل دوست 2 , رمضان واقعی 3 , فریبا استوار 4 , سعید پورکریم 5
1 - کارشناس ارشد پژوهشی
2 - کارشناس ارشد پژوهشی
3 - هیات علمی
4 - عضو هیات علمی پژوهشکده محیط زیست جهاددانشگاهی، گیلان، ایران
5 - اداره آب و فاضلاب
کلید واژه: اکسیداسیون پیشرفته, تصفیه فتوکاتالیستی, تیتانیوم دی اکسید, , کامپوزیت سیمانی,
چکیده مقاله :
حذف نیترات از آب آشامیدنی سابقه تحقیقاتی بیش از سه دهه از مطالعات محققین حوزه تصفیه آب را به خود اختصاص داده است و همچنان زمینه فعالیت بسیاری از موضوعات تحقیقاتی می باشد. هدف اصلی از مطالعه در این حوزه، دستیابی یا اصلاح روشهای حذف نیترات از آب آشامیدنی با حداقل هزینه و حداقل اثر سوء بر محیط زیست است. استفاده از فرایند فتوکاتالیستی برای نیترات زدایی موضوع جدیدی نیست، اما هنوز ابهامات زیادی درباره این موضوع مطرح می باشد. در این مطالعه، امکان سنجی کاربرد دو فتوکاتالیست مختلف بر روی بستر بتن فراتوانمند (UHPC) مورد بحث واقع شده است. این بستر جدید بوسیله ادغام شدن فتوکاتالیست در ماتریسی سیمانی که به صورت یک لایه فعال بر سطح این بتن عمل می کند، ساخته می شود. حداکثر بهرهوری و کارایی بلند مدت این سطح فعال بدون افت قابل توجه فتوکاتالیست واقع شده بر روی سطح حاصل می گردد. در این تحقیق امکان استفاده از لایههای فتوکاتالیستی بر روی عناصر ساخته شده از بتن فراتوانمند همچون کانال های آبرسانی مورد ارزیابی قرار گرفت و چالش های استفاده از چنین لایه هایی بر سطوح UHPC تشریح گردید. با توجه به تحقیقات صورت گرفته، مشخص شد که استفاده از بستر ثابت کامپوزیت سیمانی جهت تصفیه فتوکاتالیستی نسبت به سایر روش های تصفیه فتوکاتالیستی آب، دارای برتری هایی می باشد.
Denitrification of drinking water has a research history of more than three decades in the field of water treatment and is still the subject of many research projects. The main purpose of this study is to obtain or modify methods for removing nitrate from drinking water in an economic way and force minimal adverse effects on the environment. The use of photocatalytic process for denitrification is not new, but there are still many ambiguities. In this study, the feasibility of using two different photocatalysts over the ultra-high performance concrete (UHPC) substrate was discussed. This new substrate is fabricated by immobilizing the photocatalyst inside a cement matrix which acts as an active layer over the UHPC surface. Optimum long-term lifecycle and higher efficiency of this active surface is achieved without a significant drop of the photocatalyst activity near the surface. In this study, the possibility of using photocatalytic composite layers over the elements made of UHPC for applications such as water supply channels was evaluated and the challenges of using such layers on UHPC surfaces were described. According to the studies, it was found that the use of fixed cement composite bed for photocatalytic treatment has advantages over other methods of photocatalytic water treatment.
Anderson J.A., (2011), Photocatalytic nitrate reduction over Au/TiO2, Catalysis Today, 175(1) 316–321. https://doi.org/10.1016/j.cattod.2011.04.009
Andrew, J.A., Thomas, J.J., Jennings, M.H., (2007). Composition and density of nanoscale calcium silicate hydrate in cement. Nat. Mater. 35 (6), 311e316. https://doi.org/10.1038/nmat1871
Azmee N.M., Shafiq N., (2018) Ultra-high performance concrete: From fundamental to applications, Case Studies in Construction Materials, 9, 00197. https://doi.org/10.1016/j.cscm.2018.e00197
Carey J., Lawrence J., Tosine H., (1976), Photodechlorination of PCB’s in the presence of titanium dioxide in aqueous suspensions, Bulletin of Environmental Contamination and Toxicology, 16, 697–701. https://doi.org/10.1007/BF01685575
Chen J., Poon C., (2009), Photocatalytic construction and building materials: From fundamentals to applications, Building and Environment, 44, 1899-1906. https://doi.org/10.1016/j.buildenv.2009.01.002
Chen, M., Chu, J., (2011). NOx photocatalytic degradation on active concrete road surface from experiment to real-scale application. J. Clean. Prod. 19 (11), 1266e1272. https://doi.org/10.1016/j.jclepro.2011.03.001
Chiarini, A., (2012). Designing an environmental sustainable supply chain through ISO 14001 standard. Manag. Environ. Qual. Intern J. 24 (1), 16e33. https://doi.org/10.1108/14777831311291113
Chiarini, A., (2013). Strategies for developing an environmentally sustainable supply chain: differences between manufacturing and service sectors. Busin. Strat. Environ. 23(7), 493-504. https://doi.org/10.1002/bse.1799
Constantinides, G., Ulm, F.J., (2007). The nanogranular nature of C-S-H. Journal of the Mechanics and Physics of Solids, 55(1), 64-90. https://doi.org/10.1016/j.jmps.2006.06.003
Cucek, L., Klemes, J.J., Kravanja, Z., (2012). A review of footprint analysis tools for monitoring impacts on sustainability. J. Clean. Prod. 34 (1), 9e20. https://doi.org/10.1016/j.jclepro.2012.02.036
Durán, A., Monteagudo, J. M., San Martín, I. (2018). Operation costs of the solar photo-catalytic degradation of pharmaceuticals in water: A mini-review. Chemosphere, 211, 482-488. https://doi.org/10.1016/j.chemosphere.2018.07.170
Grady C.P.L., Glen T. Daigger G.T., Love N.G., Filipe C.D.M., (2011) Biological Wastewater Treatment, CRC Press, Third Ed.
Hirayama J., Abe R., Kamiya Y., (2014) Combinational effect of Pt/SrTiO3:Rh photocatalyst and SnPd/Al2O3 non-photocatalyst for photocatalytic reduction of nitrate to nitrogen in water under visible light irradiation, Appl. Catal. B-Environ. 144, 721–729. https://doi.org/10.1016/j.apcatb.2013.08.005
Janus M., Madradraszewski S., Kamila Zajac K., Kusiak-Nejman E., Morawski A.W., Stephan D., (2019) Photocatalytic Activity and Mechanical Properties of Cements Modified with TiO2/N, Materials, 12(22), 3756. https://doi.org/10.3390/ma12223756
Jennings, M.H., (2008). Refinements to colloid model of C-S-H in cement: CM-II. Cement and Concrete Research 38(3), 275-289. https://doi.org/10.1016/j.cemconres.2007.10.006
Kapoor A., Viraraghavan T., (1997) Nitrate Removal From Drinking Water—Review, J. Environ. Eng.-ASCE 123, 371–380. https://doi.org/10.1061/(ASCE)0733-9372(1997)123:4(371)
Kim, S.Y., Lim, T.M., Chang, T.S., Shin, C.H., (2007). Photocatalysis of methylene blue on titanium dioxide nanoparticles synthesized by modified sol-hydrothermal process of TiCl4. Catal. Lett. 117(3), 112-118. https://doi.org/10.1007/s10562-007-9115-8
Kominami H., Nakaseko T., Shimada Y., Furusho A., … (2005). Selective photocatalytic reduction of nitrate to nitrogen molecules in an aqueous suspension of metal-loaded titanium(iv) oxide particles, Chemical Communications, 23, 2933–2935. https://doi.org/10.1039/B502909K
Lachoff, M. Prieto, X., Nestle, F.D. and Nissner, R. (2003) Photocatalytic activity of semiconductor modified cement- influence of semiconductor type and cement aging, Applied Catalysis B: Environmental, 43(3), 205-216. https://doi.org/10.1016/S0926-3373(02)00303-X
Lee S.Y., Park S.J., (2013) TiO2 photocatalyst for water treatment applications, Journal of Industrial and Engineering Chemistry, 19, 1761–1769. https://doi.org/10.1016/j.jiec.2013.07.012
Li, C., Chang, S.J., Tai, M.Y., (2010). Surface chemistry and dispersion property of TiO2 nanoparticles. J. Am. Ceram. Soc. 93 (12), 4008e4010. https://doi.org/10.1111/j.1551-2916.2010.04222.x
Li J., Ji X., Li X., Hu X., Sun Y., Ma J., Qiao G., (2016). Preparation and photocatalytic degradation performance of Ag3PO4 with a two-step approach, Applied Surface Science, 372, 30-35. https://doi.org/10.1016/j.apsusc.2016.03.051
Lia X., Caia M., Lei Wanga L., Niua F., Yanga D., Zhang G., (2019) Evaluation survey of microbial disinfection methods in UV-LED water treatment systems, Science of The Total Environment, 659, 1415-1427. https://doi.org/10.1016/j.scitotenv.2018.12.344
Ling, T., Poon, C., (2014). Use of recycled CRT funnel glass as fine aggregate in dry mixed concrete paving blocks. J. Clean. Prod. 68 (1), 209e215. https://doi.org/10.1016/j.jclepro.2013.12.084
Luck J., Workman S., Coyne M., Higgins S., (2009). Consequences of manure filtration through pervious concrete during simulated rainfall events, Biosystems Engineering, 102, 417-423. https://doi.org/10.1016/j.biosystemseng.2008.09.034
Mansoob Khan M., Adil S.F., Al-Mayouf A., (2015). Metal oxides as photocatalysts, Journal of Saudi Chemical Society, 19(5), 462-464. https://doi.org/10.1016/j.jscs.2015.04.003
Nuhoglua A., Pekdemir T., Yildiz E., Keskinler B., Akay G., (2002) Drinking water denitrification by a membrane bio-reactor, Water Research, 36(5), 1155-1166. https://doi.org/10.1016/S0043-1354(01)00344-X
Opra, D. P., Gnedenkov, S. V., & Sinebryukhov, S. L. (2019). Recent efforts in design of TiO2 (B) anodes for high-rate lithium-ion batteries: a review. Journal of Power Sources, 442, 227225. https://doi.org/10.1016/j.jpowsour.2019.227225
Osborn, D. (2012). Quantification of NOx reduction via nitrate accumulation on a TiO2 photocatalytic concrete pavement. LSU Master's Theses. 4264. https://digitalcommons.lsu.edu/gradschool_theses/4264
Osborn, D., Hassan, M., Dylla, H., (2012). Quantification of reduction of nitrogen oxides by nitrate accumulation on titanium dioxide photocatalytic Concrete pavement. Transport. Res. Record: J. Transp. Res. Board 2290, 147e153. https://doi.org/10.3141/2290-19
Park S., Tia M., (2003), An experimental study on water-purification properties of porous concrete, Cement and Concrete Research, 34, 177 - 84. https://doi.org/10.1016/S0008-8846(03)00223-0
Pelaez M., Nolan N.T., Pillai S.C., Seery M.K., Falaras P., Kontos A.G., Dunlop P.S.M., Hamilton J.W.J., … (2012) A review on the visible light active titanium dioxide photocatalysts for environmental applications Appl. Catal. B-Environ. 125, 331–349. https://doi.org/10.1016/j.apcatb.2012.05.036
Pichat P., (2013) Photocatalysis and Water Purification: From Fundamentals to Recent Applications, Wiley-VCH, 271-294. https://doi.org/10.1002/9783527645404
Portland Cement Association, (2014). Building a Better (Cleaner) World in the 21st Century. http://www.cement.org/cement-concrete-basics/concrete-products/self-cleaning-concrete.
Scherer, G.W., (1999). Structure and properties of gels. Cement and Concrete Research, 29(8), 1149-1157. https://doi.org/10.1016/S0008-8846(99)00003-4
Shah J., Židonis A., Aggidis G., (2021) State of the art of UV water treatment technologies and hydraulic design optimisation using computational modelling, Journal of Water Process Engineering, Volume 41, 102099, https://doi.org/10.1016/j.jwpe.2021.102099
Shand M., Anderson J.A., (2013), Aqueous phase photocatalytic nitrate destruction using titania based materials: routes to enhanced performance and prospects for visible light activation Catalysis Science and Technology, 3(4) 879–899. https://doi.org/10.1039/C3CY20851F
Shen, W., Gan, G., Dong, R., Tan, Y., Chen, H., Xiao, L., (2011). Fabrication and characterization of nano colloid surfaced concrete. Mater. Struct. 44 (9), 1564-1599. https://doi.org/10.1617/s11527-011-9718-9
Sincero A.P., Sincero G.A., (2002) Physical-Chemical Treatment of Water and Wastewater, IWA Publishing Soares O.S.G.P., Órfão J.J.M., Pereira M.F.R., (2009) Bimetallic catalysts supported on activated carbon for the nitrate reduction in water: Optimization of catalysts composition, Appl. Catal. B-Environ. 91(1-2), 441–448. https://doi.org/10.1016/j.apcatb.2009.06.013
Taghavi S., Amoozadeh A., Nemati F., (2021) The first report of deep eutectic solvent (DES) nano-photocatalyst (n-TiO2-P25@TDI@DES (urea: ZnCl2)) and its application on selective oxidation of benzyl alcohols to benzaldehydes, Journal of chemical technology and biotechnology, 96(2) 384-393. https://doi.org/10.1002/jctb.6550
Taylor, H.F.W., (1993). Nanostructure of C-S-H: current status. Advanced Cement Based Materials, 1(1), 38-46. https://doi.org/10.1016/1065-7355(93)90006-A
Ulm, F.J., Vandamme, M., Bobko, C., et al., (2007). Statistical indentation techniques for hydrated nanocomposite concrete, bone and shale. Georgios Constantinides J. Am. Ceram. Soc. 90 (9), 2677-2692. https://doi.org/10.1111/j.1551-2916.2007.02012.x
Vilas, M.A., Bruque, J.M., Gonza, M., Martin, L., (2007). Sensitivity of surface roughness parameters to changes in the density of scanning points in multiscale. 107(8), 617-625. https://doi.org/10.1016/j.ultramic.2006.12.002
Ward M.H., Jones R.R., Brender J.D., Kok T.M.D., … (2018) Drinking Water Nitrate and Human Health: An Updated Review, Int. J. Environ. Res. Public Health, 15(7), 1557. https://doi.org/10.3390/ijerph15071557
Yousefi, A., Allahverdi, A., Hejazi, P., (2013). Effective dispersion of nano-TiO2 powder for enhancement of photocatalytic properties in cement mixes. Constr. Build. Mater. 41(4), 224-230. https://doi.org/10.1016/j.conbuildmat.2012.11.057
Yu, J., Low, J., Wei, X., et al., (2014). Enhanced photocatalytic CO2-reduction activity of anatase TiO2 by Co-exposed {001} and {101} facets. J. Am. Chem. Soc. 136 (25), 8839-8842. https://doi.org/10.1021/ja5044787
Zoschke K., Börnick H., Worch E., (2014) Vacuum-UV radiation at 185 nm in water treatment – A review, Water Research, 52, 131-145. https://doi.org/10.1016/j.watres.2013.12.034